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S u p r a m o l e c u l a r C h e m i s t r y a n d C a t a l y s i s
B e c a u s e o f i t s i n t e r d i s c i p l i n a r y n a t u r e , s u p r a m o l e c u l a r c h e m i s t r y i s n o w p r e v a l e n t i n m a n y s c i e n t i f i c a r e a s i n c l u d i n g c h e m i s t r y , p h y s i c s , m a t e r i a l s a n d l i f e s c i e n c e . S u p r a m o l e c u l a r c h e m i s t r y w a s l i n k e d t o biology at its initial invention, for the reason that both sciences are dominated by weak interaction and molecular recognition. Typical processes such as enzymatic catalysis featuring high catalytic activity and selectivity take place under mild conditions. These attractive properties have been a source of inspiration and longstanding proposed application of supramolecular chemistry.
The joint Sino-Dutch bilateral research project will focus on the establishment of novel supramolecular systems that are constructed and fabricated based on new principles and ingenious macrocyclic compounds or other small molecular building blocks. The program aims at the development of conceptually new supramolecular and bio-inspired systems which have applications in catalysis and energy conversion.
To achieve this, experts from the following fields are expected to provide important contributions.
1. Supramolecular Catalysis and self-assembled catalysis
Construction of self-assembled catalytic systems featuring simplicity and reversibility of preparation of catalysts, and reusability and sustainability of supramolecular catalytic processes. Fabrication of well-defined supramolecular catalysts enabling chemical transformations that are difficult or even not feasible by means of conventional catalysis.
2. Bio-inspired catalysis
Catalyst systems that function based on principles found in Nature, functional biomolecule-based small, macromolecular systems and self-assembled systems with well-defined structures, which mediate and catalyze highly efficient and stereoselective and enantioseselective chemical transformations.
3. Chemical / biological self-assembly & controllable assembly processes
Development of new physical and chemical methods to regulate chemical and biological self-assembly and disassembly processes while controlling and modulating the (multiple) physical and biological functions of assembled materials.
4. Novel host-guest systems and artificial receptors
Design and synthesis of ingenious macrocyclic, small molecular and polymeric hosts based on new concepts and synergistic non-covalent and dynamic covalent bond interactions. Design and production of function (catalysis and guest transportation) targeted host systems are highly encouraged.
5. Molecular recognition
Pursuing efficient and highly selective molecular recognition systems for advanced functional materials. Exploration and understanding of novel non-covalent bond interactions such as anion recognition and transportation, which may be relevant for understanding the novel supramolecular concepts in catalysis.
Project partners are invited to explicitly seek complementary expertise, where fundamental knowledge of chemical/biological self-assembly, host-guest systems, artificial receptors and molecular recognition are enablers for the development of new concepts in supramolecular catalysis or energy conversion processes.
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